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The word "Sheol" was not coined by the scribes of the Greek Septuagint. It is Hebrew. One reference is Strong's Concordance and Lexicon, in which its rendering in Deuteronomy 32:22 has Hebrew word ID number 7585, shin aleph vav lamed (right to left):
שְׁאֹ֣ול
Phonology of the Hebrew "aleph" is variable, and "vav" changes too, but the first and last letters' pronunciation are ancient and Biblical Hebrew as discussed in Wikipedia's Hebrew consonant list.
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Does the Old Testament word ”Sheol” have Greek or Hebrew origins?
The word ”Sheol” is of Hebrew origins. However it may be somewhat a Assyro-Babylonian loan-word for "Shu'alu.”
The word ”Sheol” was for some time regarded as an Assyro-Babylonian loan-word, "Shu'alu," having the assumed meaning "the place whither the dead are cited or bidden," or "the place where the dead are ingathered." Delitzsch, who in his earlier works advanced this view, has now abandoned it; at least in his dictionary the word is not given. The non-existence of "Shu'alu" has been all along maintained by Jensen ("Kosmologie," p. 223), and recently again by Zimmern (in Schrader," K. A. T." 3d ed., p. 636, note 4) even against Jastrow's explanation (in "Am. Jour. Semit. Lang." xiv. 165-170) that "sha'al" = "to consult an oracle," or "to cite the dead" for this purpose, whence the name of the place where the dead are. The connection between the Hebrew "Sheol" and the Assyro - Babylonian "shillan" (west), which Jensen proposed instead (in "Zeitschrift für Assyriologie," v. 131, xv. 243), does not appear to be acceptable. Zimmern (l.c.) suggests "shilu" (= "a sort of chamber") as the proper Assyrian source of the Hebrew word. On the other hand, it is certain that most of the ideas covered by the Hebrew "Sheol" are expressed also in the Assyro-Babylonian descriptions of the state of the dead, found in the myths concerning Ishtar's descent into Hades, concerning Nergal and Ereshkigal (see Jensen in Schrader, "K. B." vi., part 1, pp. 74-79) and in the Gilgamesh epic (tablets ii. and xii.; comp. also Craig, "Religious Texts," i. 79; King, Magic," No. 53).
This realm of the dead is in the earth ("erẓitu" = ; comp. Job, x. 21, 22), the gateway being in the west. It is the "land without return." It is a dark place filled with dust (see Sheol, Biblical Data); but it contains a palace for the divine ruler of this shadow-realm (comp. Job xviii. 13, 14). Seven gates guard successively the approach to this land, at the first of which is a watchman. A stream of water flows through Sheol (comp. Enoch, xvii. 6, xxii. 9; Luke xvi. 24; Ps. xviii. 5; II Sam. xxii. 5).
Thus it is obvious that "Sheol" was not coined by the Greek Septuagint, as it is of Hebrew origin.